Spectroscopy of XY(5)Z (C-4v) molecules: A tensorial formalism adapted to the O(3) superset of O-h superset of C-4v chain

Authors
Rotger, M Boudon, V Loete, M
Citation
M. Rotger et al., Spectroscopy of XY(5)Z (C-4v) molecules: A tensorial formalism adapted to the O(3) superset of O-h superset of C-4v chain, J MOL SPECT, 200(1), 2000, pp. 123-130
Citations number
16
Categorie Soggetti
Spectroscopy /Instrumentation/Analytical Sciences
Journal title
JOURNAL OF MOLECULAR SPECTROSCOPY
ISSN journal
00222852 → ACNP
Volume
200
Issue
1
Year of publication
2000
Pages
123 - 130
Database
ISI
SICI code
0022-2852(200003)200:1<123:SOX(MA>2.0.ZU;2-3
Abstract
A tensorial formalism adapted to the case of XY(5)Z symmetric tops has been developed as an extension of the usual one for the octahedral molecules. W e use the O(3) superset of O-h superset of C-4 nu group chain. All the coup ling coefficients and formulas for the computation of matrix elements are g iven for this chain. Such relations are also deduced in the C-4 nu group it self. (C) 2000 Academic Press.