Population trapping in the ground state spin sublevels of Cr3+ in ruby at l
iquid helium temperature is considered. It is proposed to excite the R-1-tr
ansition by a bichromatic laser beam with an optical frequency difference m
atching the ground state spin sublevels splitting. If the excitation is str
ong enough to decouple Cr3+ from its environment, responsible for dephasing
, an appreciable amount of the population is trapped in a particular superp
osition of the spin sublevels. This superposition state does not interact w
ith the laser beam because of the destructive interference of the quantum p
aths constituting the transition. Population trapping can be detected by th
e reduced luminescence from the excited state and by the magnetization ring
ing originating from the ground state spin coherence.