Phosphino-urea chemistry: preparation and structure of chelate and P-N bond cleavage complexes

Authors
Slawin, AMZ Wainwright, M Woollins, JD
Citation
Amz. Slawin et al., Phosphino-urea chemistry: preparation and structure of chelate and P-N bond cleavage complexes, NEW J CHEM, 24(2), 2000, pp. 69-71
Citations number
11
Categorie Soggetti
Chemistry
Journal title
NEW JOURNAL OF CHEMISTRY
ISSN journal
11440546 → ACNP
Volume
24
Issue
2
Year of publication
2000
Pages
69 - 71
Database
ISI
SICI code
1144-0546(200002)24:2<69:PCPASO>2.0.ZU;2-V
Abstract
Reactions of Ph2PNRC(E)NRPPh2 proceed to give simple P,P chelate complexes when E = O but give the unexpected five-membered true heterocycle Pt[Ph2PN( Me)C(NMeH)S] Cl-2 and an unusual six-membered Pd2P2O2 ring when E = S. The X-ray structures of three examples are reported.