Formation of homoallyl stannanes via palladium-catalyzed stannylative cyclization of enynes

Authors
Lautens, M Mancuso, J
Citation
M. Lautens et J. Mancuso, Formation of homoallyl stannanes via palladium-catalyzed stannylative cyclization of enynes, ORG LETT, 2(5), 2000, pp. 671-673
Citations number
16
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
ORGANIC LETTERS
ISSN journal
15237060 → ACNP
Volume
2
Issue
5
Year of publication
2000
Pages
671 - 673
Database
ISI
SICI code
1523-7060(20000309)2:5<671:FOHSVP>2.0.ZU;2-N
Abstract
[GRAPHICS] Treatment of 1,6-enynes with tri(N-butyl)tin hydride in the presence of a c atalytic amount of palladium acetate leads to the formation of exo-methylen ecyclopentanes bearing a tri(n-butyl)stannylmethyl moiety.