R. Takahashi et al., Measurement of the diffusion coefficient of nickel nitrate in wet silica gel using UV/VIS spectroscope equipped with a flow cell, PHYS CHEM P, 2(6), 2000, pp. 1199-1204
A novel technique for the measurement of the diffusion coefficient of a sol
ute in a transparent wet-gel monolith was developed by analyzing the decay
behavior of the absorbance of the gel plate in a flow cell. The diffusion c
oefficient of a Ni(NO3)(2) in a wet silica gel is estimated by fitting the
absorbance-time data with an exponential function. The efficiency of the te
chnique was ensured by testing the effects of several measurement condition
s, such as the flow rate of the external solution and the thickness of the
gel plate. The diffusion coefficient of Ni(NO3)(2) in wet silica gel is 6.0
x10(-10) s(-1) at 20 degrees C, which is ca. 60% of that in bulk solution.
The data suggest that the silica gel network allows relatively fast transpo
rt of the liquid phase.