H. Oughaddou et al., Ge tetramer structure of the p(2 root 2x4 root 2)R45 degrees surface reconstruction of Ge/Ag(001): A surface x-ray diffraction and STM study, PHYS REV B, 61(8), 2000, pp. 5692-5697
The surface atomic structure of the p(2 root 2X4 root 2)R45 degrees superst
ructure obtained at 0.5-monolayer coverage by deposition of germanium on th
e Ag(001) surface at room temperature has been investigated using surface x
-ray diffraction and scanning tunneling microscopy. A structural model is p
roposed with clusters of four Ge atoms preferentially adsorbed near hollow
and bridge sites on the surface. The Ge-Ag bond strength is sufficient to i
nduce rearrangement of the Ag atoms in the uppermost layers and stabilize t
he reconstruction.