The magnetic and transport properties of pyrochlore R2Mo2O7 have been studi
ed with variation of the rare earth (R). The change of the mean ionic radiu
s of R, which induces change of the lattice structure, determines the magne
tic ground state (ferromagnetic or spin glass), and the magnetic phase boun
dary is correlated with the metal-insulator crossover. Furthermore, we foun
d enhanced magnetoresistance and unusual residual anomalous Hall effect at
low temperatures near the phase boundary, which can be attributed to the co
existence of both phases.