Viscous sintering phenomena in liquid-liquid dispersions

Citation
J. Philip et al., Viscous sintering phenomena in liquid-liquid dispersions, PHYS REV L, 84(9), 2000, pp. 2018-2021
Citations number
13
Categorie Soggetti
Physics
Journal title
PHYSICAL REVIEW LETTERS
ISSN journal
00319007 → ACNP
Volume
84
Issue
9
Year of publication
2000
Pages
2018 - 2021
Database
ISI
SICI code
0031-9007(20000228)84:9<2018:VSPILD>2.0.ZU;2-G
Abstract
We present experimental evidence for viscous sintering phenomena in a gel f ormed by highly viscous emulsion droplets. When a rupturing agent is added to the initially stable emulsion, a gel forms, which further contracts by p reserving the geometry of the container. The initial stages of densificatio n (up to 60%) follow very well the "cylindrical model" for viscous sinterin g, but deviate at the final stages of densification. The observed inverse d ependence of the contraction rate on viscosity is consistent with the visco us sintering theory.