Basis functions of a new type-specifically, exponential-trigonometric funct
ions depending on all six interparticle distances-have been proposed for th
e Coulomb four-body problem. A method has been developed for computing nine
-dimensional integrals determining the matrix elements of the Hamiltonian f
or a four-body system and featuring these functions. The efficiency of the
approach that relies on the proposed basis functions has been tested by cal
culating the e(+)e(-)e(+)e(-), p(+)mu(-)p(+)mu(-), mu(+)e(-)mu(+)e(-), and
p(+)e(-)p(+)e(-) molecules. (C) 2000 MAIK ''Nauka/Interperiodica".