Reactivity of cis-diaminedichloroplatinum(II) (cis-platin) towards chromium(VI)

Authors
Stawinska, J Staszak, Z Jezierska, J Cieslak-Golonka, M Daszkiewicz, M
Citation
J. Stawinska et al., Reactivity of cis-diaminedichloroplatinum(II) (cis-platin) towards chromium(VI), POL J CHEM, 74(3), 2000, pp. 291-301
Citations number
33
Categorie Soggetti
Chemistry
Journal title
POLISH JOURNAL OF CHEMISTRY
ISSN journal
01375083 → ACNP
Volume
74
Issue
3
Year of publication
2000
Pages
291 - 301
Database
ISI
SICI code
0137-5083(200003)74:3<291:ROC(TC>2.0.ZU;2-D
Abstract
The interaction of CI (VI) compounds: K2Cr2O7 and KCrO3Cl with cis-diamined ichloroplatinum(II) (cis-platin) has been studied spectroscopically (UV-VIS , IR, FIR, ESR). It was found that the redox processes took place with the precipitation of brown Pt(IV)-Cr(III) heteropolynuclear products. The decon volution of the electronic spectra allowed the analysis ill convention of i ndependent Pt(IV) and Cr(III) crystal fields.