The development of polymer optical fiber (POF) leads to the fundamental que
stion about the transmission loss limit of amorphous polymer glasses. The t
wo important intrinsic loss factors in amorphous polymer optical fibers are
molecular vibration absorption and scattering due to fluctuation. In this
paper, we have investigated the lower limit of the inherent light transmiss
ion loss of amorphous polymer glass from its molecular structure by using t
he Morse potential theory for absorption and the fluctuation theory for sca
ttering. The theoretical lower limit of the attenuation of the amorphous pe
rfluoropolymer is 0.3 dB km(-1) at 1.3 mu m, and is comparable with that of
silica fiber. Amorphous perfluoropolymer seems to be a most transparent po
lymer.