Synthesis and structural characterization of the complexes of 2-alkoxycarbonylpropyltin trichlorides with hexamethylphosphoramide and N-(2-hydroxyphenyl)-2-hydroxy-1-naphthylaldimine

Authors
Tian, LJ Zhou, ZY Zhao, B Sun, HT Yu, WT Yang, P
Citation
Lj. Tian et al., Synthesis and structural characterization of the complexes of 2-alkoxycarbonylpropyltin trichlorides with hexamethylphosphoramide and N-(2-hydroxyphenyl)-2-hydroxy-1-naphthylaldimine, SYN REAC IN, 30(2), 2000, pp. 307-317
Citations number
24
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
SYNTHESIS AND REACTIVITY IN INORGANIC AND METAL-ORGANIC CHEMISTRY
ISSN journal
00945714 → ACNP
Volume
30
Issue
2
Year of publication
2000
Pages
307 - 317
Database
ISI
SICI code
0094-5714(2000)30:2<307:SASCOT>2.0.ZU;2-I
Abstract
The complexes of 2-alkoxycarbonylpropyltin trichlorides with hexamethylphos phoramide (HMPA) and N-(2-hydroxyphenyl)-2-hydroxy-1-naphthylaldimine (H2L) have been synthesized and characterized by means of elemental analyses, IR and H-1 NMR spectra and an X-ray single crystal diffraction study. The spe ctral data indicate that these complexes are all six-coordinate tin compoun ds. The crystal structure of MeOCO-CH(CH3)CH2SnCl3. HMPA shows that the tin atom adopts a distorted octahedral geometry via the oxygen atoms of HMPA a nd intramolecular carbonyl group.