Preparation and characterization of a novel complex of molybdenum(V) with homocitrate, K-5(NH4)[MO2O2S2(C7H6O7)(2)]center dot 4H(2)O

Authors
Li, DM Xu, JQ Li, ZC Xing, YH Wang, RZ Liu, SQ Sun, HR Wang, TG
Citation
Dm. Li et al., Preparation and characterization of a novel complex of molybdenum(V) with homocitrate, K-5(NH4)[MO2O2S2(C7H6O7)(2)]center dot 4H(2)O, SYN REAC IN, 30(2), 2000, pp. 319-333
Citations number
30
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
SYNTHESIS AND REACTIVITY IN INORGANIC AND METAL-ORGANIC CHEMISTRY
ISSN journal
00945714 → ACNP
Volume
30
Issue
2
Year of publication
2000
Pages
319 - 333
Database
ISI
SICI code
0094-5714(2000)30:2<319:PACOAN>2.0.ZU;2-S
Abstract
A new binuclear molybdenum-sulfur complex with homocitrate, K-5(NH4)[Mo2O2S 2(C7H6O7)(2)]. 4H(2)O, was synthesized and characterized by elemental analy ses, spectroscopy (infrared, UV-Visible, H-1 and C-13 NMR, XPS and EPR), an d TG-DTA. According to the proposed binuclear structure of the compound, ea ch octahedral molybdenum atom is coordinated to hydroxyl, alpha-carboxylate and beta-carboxylate groups of a homocitrate molecule, two bridging-sulfur atoms and a terminal oxygen atom.