Ih. Cho et al., Syntheses and optical characterization of poly[1,8-octanedioxy-1,4-phenylene-1,2-ethylene-1,4-phenylene] and its copolymer derivatives, THIN SOL FI, 363(1-2), 2000, pp. 138-142
We have investigated the optical properties of a series of poly(p-phenylene
vinylene) (PPV) copolymers. Three-wide bandgap PPV copolymers were synthes
ized and characterized. The new PPV copolymers showed a large blue shift in
both absorption and emission that their average bandgap is over 3.1 eV. A
significant solvatochromic effect was observed in the photoluminescence (PL
) spectra of copolymers. The dimethoxy-substituted copolymer showed the hig
hest quantum efficiency and processability among three copolymers. (C) 2000
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