The application of hyperfine interaction techniques to problems in solid st
ate physics has been steadily growing over the last decade with the use of
radioactive ion beam facilities such as ISOLDE at CERN. New applications of
the e(-)-gamma Perturbed Angular Correlation (PAC) technique are underway
at ISOLDE using probe nuclei with highly converted cascades. In this paper
we present the motivation for extending PAC experiments to elements/isotope
s not usable with the conventional gamma-gamma PAC technique. Examples will
be shown where the long-lived As-73/Ge-73, the short lived Ba-127/Cs-127 a
nd the Hg-197m/Hg-197 decay cascades are applied to measurements of nuclear
quadrupole interactions in materials.