M. Mizuno et al., Water molecular motion and hydrogen bond in paramagnetic [Cu(H2O)(6)][PtCl6] as studied by single crystal H-2 NMR, Z NATURFO A, 55(1-2), 2000, pp. 178-182
Citations number
17
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
ZEITSCHRIFT FUR NATURFORSCHUNG SECTION A-A JOURNAL OF PHYSICAL SCIENCES
The temperature and angular dependences of the H-2 NMR spectrum were measur
ed for single crystal [Cu(H2O)(6)][PtCl6]. (e(2)Qq/h, eta) = (132 kHz, 0.72
) were obtained for the D nucleus averaged by the fast 180 degrees flip of
the water molecule at 297 K. D-1(236 kHz, 0.10) and D-2(246 kHz, 0.09) were
obtained for two unequal D nuclei of the water molecule at 133 K. Below T-
c, at least three nonequivalent waters were found to exist. The jumping rat
e for the 180 degrees flip of the water molecule (k) was obtained from the
simulation of H-2 NMR spectra at H0\\[111] direction. The activation energy
E-a and the jumping rate at infinite temperature were estimated from the t
emperature dependence of k to be 24kJmol(-1) and 1 x 10(13)s(-1).