P. Sostrand et al., Hazardous peak concentrations of hydrogen sulfide gas related to the sewage purification process, AM IND HYG, 61(1), 2000, pp. 107-110
The concentration of hydrogen sulfide in the atmosphere of a sewage purific
ation plant in Norway was studied. Continuous measurements over several 3-w
eek periods showed that the concentrations generally were lower than 2 ppm,
but peak concentrations over 100 ppm were discovered. Rapid onset and decl
ine characterized these peak concentrations, which occurred at regular inte
rvals. Through evaluation of the time pattern of these peaks compared with
plant operations, a specific process was identified as the likely causative
factor of the spikes. Through simple remedial actions the hydrogen sulfide
concentration associated with this activity was reduced from above 100 ppm
to less than 2 ppm. Olfactory fatigue to hydrogen sulfide and strong offen
sive odors from other compounds in the sewage makes smell ineffective for s
ignaling high concentrations. Peak concentrations may therefore pass unnoti
ced unless detected with continuous measuring equipment. The risk for expos
ure may be reduced by enclosing processes and through the use of spot extra
ction ventilation in areas with compacted anaerobic waste material.