Catalytic conversions in water Part 13. Aerobic oxidation of olefins to methyl ketones catalysed by a water-soluble palladium complex - mechanistic investigations

Authors
ten Brink, GJ Arends, IWCE Papadogianakis, G Sheldon, RA
Citation
Gj. Ten Brink et al., Catalytic conversions in water Part 13. Aerobic oxidation of olefins to methyl ketones catalysed by a water-soluble palladium complex - mechanistic investigations, APP CATAL A, 194, 2000, pp. 435-442
Citations number
43
Categorie Soggetti
Physical Chemistry/Chemical Physics","Chemical Engineering
Journal title
APPLIED CATALYSIS A-GENERAL
ISSN journal
0926860X → ACNP
Volume
194
Year of publication
2000
Pages
435 - 442
Database
ISI
SICI code
0926-860X(20000313)194:<435:CCIWP1>2.0.ZU;2-X
Abstract
Water-soluble palladium(II) bathophenanthroline is a stable, recyclable cat alyst for the selective aerobic oxidation of terminal olefins to the corres ponding 2-alkanones in a biphasic liquid-liquid system. Kinetic measurement s indicate that the active catalyst is a homogeneous mononuclear species. ( C) 2000 Elsevier Science B.V. All rights reserved.