The formation of porous silicon is investigated by the Monte Carlo met
hod in a model that takes account of the nonuniformity of the charge d
istribution over the silicon-electrolyte interface, hole diffusion, ge
neration, and recombination processes, and size quantization. The stru
ctures obtained in a computer simulation for various doping levels of
the crystalline substrate, temperatures, HF concentrations, and anode
current densities are presented. Analysis of nanoporous structures sho
ws that the porosity depends on the depth and reveals the presence of
a fractal dimensionality on scales of less than 10 nm. (C) 1997 Americ
an Institute of Physics.