X-ray spectrometry combined with a fundamental parameter package can b
e used to obtain semiquantitative analytical results for thin layered
samples. This paper explores the use of the program FPMulti for variou
s applications. These applications are examples of how accurate this p
rogram is for multilayer and thin film analysis. After a short descrip
tion of the analytical method, the range of applications is given with
which the authors have experience. In the experimental section three
applications are described in more detail: (i) an example to show the
accuracy of the method, (ii) an example of the calculation of the laye
r thickness and (iii) the possibility of quantifying oxygen in 3d meta
l oxides. (C) 1997 by John Wiley & Sons, Ltd.