Intramolecular Diels-Alder reactions of masked p-benzoquinones: a novel methodology for the synthesis of highly functionalized cis-decalins

Citation
Yf. Tsai et al., Intramolecular Diels-Alder reactions of masked p-benzoquinones: a novel methodology for the synthesis of highly functionalized cis-decalins, CHEM COMMUN, (6), 2000, pp. 475-476
Citations number
26
Categorie Soggetti
Chemistry
Journal title
CHEMICAL COMMUNICATIONS
ISSN journal
13597345 → ACNP
Issue
6
Year of publication
2000
Pages
475 - 476
Database
ISI
SICI code
1359-7345(2000):6<475:IDROMP>2.0.ZU;2-O
Abstract
Tethering of dienols to hydroquinones under Mitsunobu conditions followed b y oxidation with diacetoxyiodobenzene in methanol resulted in the developme nt of highly functionalized cis-decalins via intramolecular Diels-Alder rea ctions of in situ generated masked p-benzoquinones.