Enantioselective deprotonation reactions using a novel homochiral magnesium amide base

Authors
Henderson, KW Kerr, WJ Moir, JH
Citation
Kw. Henderson et al., Enantioselective deprotonation reactions using a novel homochiral magnesium amide base, CHEM COMMUN, (6), 2000, pp. 479-480
Citations number
19
Categorie Soggetti
Chemistry
Journal title
CHEMICAL COMMUNICATIONS
ISSN journal
13597345 → ACNP
Issue
6
Year of publication
2000
Pages
479 - 480
Database
ISI
SICI code
1359-7345(2000):6<479:EDRUAN>2.0.ZU;2-O
Abstract
A novel homochiral magnesium bisamide base system has been prepared and rea cted with a series of prochiral ketones in the presence of TMSCl to give ef ficient formation of the corresponding enol ethers in enantiomeric ratios o f up to 95:5.