We study Kontsevich's deformation quantization for the dual of a finite-dim
ensional Lie algebra g. Regarding elements of S(g) as distributions on g, w
e show that the *-multiplication operator (r bar right arrow r * p) is a di
fferential operator with analytic germ at 0. We use this to establish a con
jecture of Kashiwara and Vergne which, in turn, gives a new proof of Duflo'
s result on the local solvability of bi-invariant differential operators on
a Lie group. (C) 2000 Academie des sciences/Editions scientifiques et medi
cales Elsevier SAS.