HYDROXYL-DIRECTED STEREOCOMPLEMENTARY PINACOL CYCLIZATIONS MEDIATED BY SMI2

Authors
KAWATSURA M KISHI E KITO M SAKAI T SHIRAHAMA H MATSUDA F
Citation
M. Kawatsura et al., HYDROXYL-DIRECTED STEREOCOMPLEMENTARY PINACOL CYCLIZATIONS MEDIATED BY SMI2, Synlett, (5), 1997, pp. 479
Citations number
18
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Synlett → ACNP
ISSN journal
09365214
Issue
5
Year of publication
1997
Database
ISI
SICI code
0936-5214(1997):5<479:HSPCMB>2.0.ZU;2-C
Abstract
The decalin rings were cyclized with complete stereocontrol about the new chiral centers through the hydroxyl-directed pinacol couplings pro moted by SmI2. In these annulation reactions, stereocomplementarity wa s observed depending on the absence or presence of HMPA.