ORIGINAL SYNTHESIS OF 1,2-OXATHIOLAN-2-OXIDES AND VINYL CYCLOPROPANE CARBOXYLIC ESTERS

Authors
Citation
A. Krief et L. Provins, ORIGINAL SYNTHESIS OF 1,2-OXATHIOLAN-2-OXIDES AND VINYL CYCLOPROPANE CARBOXYLIC ESTERS, Synlett, (5), 1997, pp. 505
Citations number
15
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
ISSN journal
09365214
Issue
5
Year of publication
1997
Database
ISI
SICI code
0936-5214(1997):5<505:OSO1AV>2.0.ZU;2-F
Abstract
1,2-Oxathiolan-2-oxides or vinyl cyclopropane carboxylic esters are pr epared chemoselectively and in rather good yields from methyl 2,4-pent adienoate, tributylstannyllithium and carbonyl compounds. The later ar e formally deoxygenated in the process and play the role of carbenes.