Origin of magnetic field effect in the photolysis of 7-silanorbornadiene derivatives in solution

Authors
Taraban, MB Kruppa, AI Volkova, OS Ovcharenko, IV Musin, RN Leshina, TV Korolenko, EC Kitahara, K
Citation
Mb. Taraban et al., Origin of magnetic field effect in the photolysis of 7-silanorbornadiene derivatives in solution, J PHYS CH A, 104(9), 2000, pp. 1811-1816
Citations number
15
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
JOURNAL OF PHYSICAL CHEMISTRY A
ISSN journal
10895639 → ACNP
Volume
104
Issue
9
Year of publication
2000
Pages
1811 - 1816
Database
ISI
SICI code
1089-5639(20000309)104:9<1811:OOMFEI>2.0.ZU;2-U
Abstract
Theoretical modeling of the magnetic field effect detected in the photolysi s of 7-silanorbornadiene derivatives has clearly demonstrated the involveme nt of biradical intermediates and confirmed the participation of both singl et and triplet excited states of dimethylsilylene, :SiMe2.