Structure of spinel

Citation
Ke. Sickafus et al., Structure of spinel, J AM CERAM, 82(12), 1999, pp. 3279-3292
Citations number
75
Categorie Soggetti
Apllied Physucs/Condensed Matter/Materiales Science","Material Science & Engineering
Journal title
JOURNAL OF THE AMERICAN CERAMIC SOCIETY
ISSN journal
00027820 → ACNP
Volume
82
Issue
12
Year of publication
1999
Pages
3279 - 3292
Database
ISI
SICI code
0002-7820(199912)82:12<3279:SOS>2.0.ZU;2-H
Abstract
This paper reviews the crystal structure of compounds with the general form ula AB(2)X(4), which crystallize with the same atomic structure as the mine ral spinel, MgAl2O4. Three degrees of freedom associated with the detailed atomic arrangements of spinels are considered here: (i) the lattice paramet er, a; (ii) the anion parameter, a; and (iii) the cation inversion paramete r, i. Oxide spinels are used as examples to explore the interrelationships between these parameters.