Dp. Fairchild et al., The mechanism of brittle fracture in a microalloyed steel: Part I. Inclusion-induced cleavage, MET MAT T A, 31(3), 2000, pp. 641-652
The cleavage resistance of two microalloyed steels (steels A and B) was stu
died using several tests, including the instrumented precracked Charpy and
Charpy V-notch (CVN) techniques. Ductile-to-brittle transition temperatures
were measured for the base-metal and simulated heat-affected zone (HAZ) mi
crostructures. Steel B showed inferior cleavage resistance to steel A, and
this could not be explained by differences in gross microstructure. Scannin
g electron fractography revealed that TiN inclusions were responsible for c
leavage initiation in steel B. These inclusions were well bonded to the fer
ritic matrix. It is believed that a strong inclusion-matrix bond is a key f
actor in why TiN inclusions are potent cleavage initiators in steel. Strong
bonding allows high stresses in a crack/notch-tip plastic zone to act on t
he inclusions without debonding the interface. Once an inclusion cleaves, t
he strong bond allows for transfer of the TiN crack into the ferritic matri
x. It was estimated that only 0.0016 wt pet Ti was tied up in the offending
inclusions in steel B. This indicates that extended times at high temperat
ures during the casting of such steels could produce TiN-related toughness
deterioration at even modest Ti contents.