Synthesis of (boryl)(silyl)iminomethanes by insertion of isonitriles into silicon-boron bonds

Authors
Suginome, M Fukuda, T Nakamura, H Ito, Y
Citation
M. Suginome et al., Synthesis of (boryl)(silyl)iminomethanes by insertion of isonitriles into silicon-boron bonds, ORGANOMETAL, 19(5), 2000, pp. 719-721
Citations number
21
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
ORGANOMETALLICS
ISSN journal
02767333 → ACNP
Volume
19
Issue
5
Year of publication
2000
Pages
719 - 721
Database
ISI
SICI code
0276-7333(20000306)19:5<719:SO(BIO>2.0.ZU;2-7
Abstract
The insertion of alkyl and aryl isonitriles into the silicon-boron bond of silylboranes proceeded thermally to provide (boryl)(silyl)iminomethanes in moderate-to-good yields. The (boryl)(silyl)iminomethane reacted with borane (BH3) to give the corresponding borane complex in good yield, whose crysta l structure was determined by a single-crystal X-ray analysis.