Citation
H. Hatop et al., Syntheses and structures of new organoaluminum fluorides, ORGANOMETAL, 19(5), 2000, pp. 937-940
Citations number
27
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
ORGANOMETALLICS
ISSN journal
02767333
→ ACNP
Volume
19
Issue
5
Year of publication
2000
Pages
937 - 940
Database
ISI
SICI code
0276-7333(20000306)19:5<937:SASONO>2.0.ZU;2-7
Abstract
This paper reports the synthesis of (Cp2ZrMe)(mu-F)[(Me3Si)(3)CAlF2] (1), [
(Cp2Zr)(mu-F)(2)[(Me3Si)(3)CAlF]](2)O (2), and [Na(Me3Si)(3)CAlF3(THF)(])4
(3). 1 was prepared by the reaction of [(M(3)eSi)(3)CAlF2](3) with Cp2ZrMe2
and Me3SnF. Compound 1 reacts with THF to form 2. The reaction of (Me3Si)(
3)CAlMe2(THF) with Me3SnF and NaCl affords 3. The molecular structures of c
ompounds 1-3 have been determined by single-crystal X-ray structural analys
is.