We present systematic ab initio calculations for the magnetic moments of 3d
and 4d transition-metal impurities on the high-moment ferromagnetic phase
of fee Fe/Cu(100) surface. We find that on this substrate the moments of th
e impurities are in general larger than on bcc Fe. Furthermore the transiti
on from antiferromagnetic to ferromagnetic coupling occurs at smaller valen
cies. A very subtle behavior is found for Ru nanostructures, which show fer
romagnetic coupling for adatoms and linear chains, but antiferromagnetic co
upling for larger islands and monolayers.