Unexpected scenario of glass transition in polymer globules: An exactly enumerable model

Citation
R. Du et al., Unexpected scenario of glass transition in polymer globules: An exactly enumerable model, PHYS REV L, 84(11), 2000, pp. 2417-2420
Citations number
20
Categorie Soggetti
Physics
Journal title
PHYSICAL REVIEW LETTERS
ISSN journal
00319007 → ACNP
Volume
84
Issue
11
Year of publication
2000
Pages
2417 - 2420
Database
ISI
SICI code
0031-9007(20000313)84:11<2417:USOGTI>2.0.ZU;2-E
Abstract
We introduce a lattice model of glass transition in polymer globules. This model exhibits ergodicity breaking in which the disjoint regions of phase s pace do not arise uniformly, but as small chambers whose number increases e xponentially with polymer density. Chamber sizes obey power law distributio n, making phase space similar to a fractal foam. This clearly demonstrates the importance of the phase space geometry and topology in describing any g lass-forming system, such as semicompact polymers during protein folding.