M. Sahana et al., GIANT MAGNETORESISTANCE IN LA0.6PB0.4MN(1-X)TIXO3 FILMS - ENHANCEMENTOF MAGNETORESISTANCE DUE TO TI4+ SUBSTITUTION IN MN4+ SITES, Materials research bulletin, 32(7), 1997, pp. 831-837
Nonmagnetic Ti4+ ion is substituted for Mn4+ in La0.6Pb0.4MnO3. The re
sulting La0.6Pb0.4Mn(1-x)TixO3 (0 less than or equal to x less than or
equal to 0.3) crystallizes in rhombohedral structure. The insulator-t
o-metal transition temperature decreases from 320 K to 92 K as x is va
ried from 0 to 0.09. Epitaxial films for the compositions x = 0, 0.03,
0.05, and 0.07 are fabricated by pulsed-laser deposition. Magnetoresi
stance at 6 T is enhanced from 38% for x = 0 to 75% for x = 0.07. The
presence of Ti4+ (d(0)) ion decreases the Mn-Mn interaction through ox
ygen and thereby affects the resistivity and magnetoresistance of La0.
6Pb0.4MnO3. (C) 1997 Elsevier Science Ltd.