Optically active transition metal complexes, 122. Synthesis of palladium(II) complexes with Schiff base ligands - Intramolecular interactions

Authors
Brunner, H Niemetz, M Zabel, M
Citation
H. Brunner et al., Optically active transition metal complexes, 122. Synthesis of palladium(II) complexes with Schiff base ligands - Intramolecular interactions, Z NATURFO B, 55(2), 2000, pp. 145-154
Citations number
15
Categorie Soggetti
Chemistry
Journal title
ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES
ISSN journal
09320776 → ACNP
Volume
55
Issue
2
Year of publication
2000
Pages
145 - 154
Database
ISI
SICI code
0932-0776(200002)55:2<145:OATMC1>2.0.ZU;2-5
Abstract
Imines of salicylaldehyde and 2,6-diformyl-p-cresol have been used as ligan ds in palladium(II) complexes. Enantiomerically pure ligands give enantiome rically pure complexes, racemic ligands give racemates and meso-forms. Diff erences between the respective isomers of the ligands within the complexes and between the diastereomers of the complexes were investigated. Crystal s tructure analyses established the trans configuration at the metal center.