H. Brunner et al., Optically active transition metal complexes, 122. Synthesis of palladium(II) complexes with Schiff base ligands - Intramolecular interactions, Z NATURFO B, 55(2), 2000, pp. 145-154
Citations number
15
Categorie Soggetti
Chemistry
Journal title
ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES
Imines of salicylaldehyde and 2,6-diformyl-p-cresol have been used as ligan
ds in palladium(II) complexes. Enantiomerically pure ligands give enantiome
rically pure complexes, racemic ligands give racemates and meso-forms. Diff
erences between the respective isomers of the ligands within the complexes
and between the diastereomers of the complexes were investigated. Crystal s
tructure analyses established the trans configuration at the metal center.