The separation and recognition mechanism of derivatized secondary alcoholson a permethylated beta-cyclodextrin stationary phase

Authors
Jiang, YJ Zhou, LM Wang, QH Zhu, DQ Liu, XL
Citation
Yj. Jiang et al., The separation and recognition mechanism of derivatized secondary alcoholson a permethylated beta-cyclodextrin stationary phase, ACT CHIM S, 58(2), 2000, pp. 240-242
Citations number
8
Categorie Soggetti
Chemistry
Journal title
ACTA CHIMICA SINICA
ISSN journal
05677351 → ACNP
Volume
58
Issue
2
Year of publication
2000
Pages
240 - 242
Database
ISI
SICI code
0567-7351(2000)58:2<240:TSARMO>2.0.ZU;2-E
Abstract
Thirty nine derivatized secondary alcohols have been separated on a capilla ry column coated with permethylated beta - cyclodextrin. The influence of a lpha values with the derivatized groups, the position of chiral center in t he chain and the number of carbon atoms on enantioselectivity were discusse d. The enantioselectivity of isobutyryl derivatives of secondary alcohols i nvestigated decrease apparently.