THE USE OF HOMOCHIRAL 2-METHYLENE-4,5-DIARYL-1,3-DIOXOLANES AS RECYCLABLE ACETIC ESTER ENOLATE EQUIVALENTS - ASYMMETRIC-SYNTHESIS OF TERPENOIDS

Authors
HAYES P LI KD LEEMING P WALLACE TW
Citation
P. Hayes et al., THE USE OF HOMOCHIRAL 2-METHYLENE-4,5-DIARYL-1,3-DIOXOLANES AS RECYCLABLE ACETIC ESTER ENOLATE EQUIVALENTS - ASYMMETRIC-SYNTHESIS OF TERPENOIDS, Tetrahedron letters, 38(24), 1997, pp. 4309-4310
Citations number
2
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
38
Issue
24
Year of publication
1997
Pages
4309 - 4310
Database
ISI
SICI code
0040-4039(1997)38:24<4309:TUOH2A>2.0.ZU;2-N
Abstract
The alpha-cyclocitral derivatives 5 and 10 are accessible in homochira l form via an auxiliary-based sequence using the heterodiene cycloaddi tion of a 2-methylene-4,5-diaryl-1,3-dioxolane 1 to 2-formyl-4,4-dimet hyl-2-cyclohexen-1-one 2 as the key step. (C) 1997 Elsevier Science Lt d.