The molecular beam epitaxy of cubic GaN on Si(001) substrates, which were c
overed by a 4 nm thick beta-SiC layer, is reported. The structural and opti
cal properties of the cubic GaN epilayers were studied by transmission elec
tron microscopy, high-resolution x-ray diffraction, and low-temperature pho
toluminescence measurements. We find clear evidence for the growth of cubic
GaN layers almost free of hexagonal inclusions. The density of extended de
fects and the near band edge photoluminescence of the cubic GaN layers grow
n at substrate temperatures of 835 degrees C is comparable to that of high
quality cubic GaN epilayers grown by molecular beam epitaxy on GaAs (001) s
ubstrates. (C) 2000 American Institute of Physics. [S0003-6951(00)03413-6].