REACTION OF DIMETHYL SULFIDE DITRIFLATE WITH ALKENES - SYNTHESIS OF SULFUR DERIVATIVES OF NORTRICYCLANE

Authors
NENAJDENKO VG VERTELEZKIJ PV GRIDNEV ID SHEVCHENKO NE BALENKOVA ES
Citation
Vg. Nenajdenko et al., REACTION OF DIMETHYL SULFIDE DITRIFLATE WITH ALKENES - SYNTHESIS OF SULFUR DERIVATIVES OF NORTRICYCLANE, Tetrahedron, 53(24), 1997, pp. 8173-8180
Citations number
20
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron → ACNP
ISSN journal
00404020
Volume
53
Issue
24
Year of publication
1997
Pages
8173 - 8180
Database
ISI
SICI code
0040-4020(1997)53:24<8173:RODSDW>2.0.ZU;2-4
Abstract
The reaction of dimethyl sulfide ditriflate with alkenes leads to the corresponding sulfonium salts. Dependence of the reaction course on th e substrate structure is discussed. In the reactions with norbornene a nd norbornadiene the sulfonium salts with nortricyclene skeleton were obtained. The configurations of the two isomeric disubstituted nortric yclanes 21a,b were determined by NMR. (C) 1997 Elsevier Science Ltd.