M. Boudart, From the century of the rate equation to the century of the rate constants: a revolution in catalytic kinetics and assisted catalyst design, CATAL LETT, 65(1-3), 2000, pp. 1-3
In the past, rate constants were extracted from rate equations obtained by
fitting kinetic data. In the future, they will be calculated by computation
al chemistry or measured by surface science techniques. They will be used f
or the start-up of a microkinetic analysis in a combinatorial iteration for
the development of optimized catalysts.