M. Fedurco et al., Reactions of photoexcited C-60 with weak organic acids. Novel method for the derivatization of fullerenes, CHEM P LETT, 319(3-4), 2000, pp. 309-317
Pyrex-filtered irradiation of C-60 solutions in liquid diphenylmethane in t
he absence of oxygen is shown to result in Ph,CH. radicals, which further r
eact with the electron-deficient C-60 to give Ph2CH-C60Hn (n = 1, 3, 5). Th
e fullerene ground state to C-3(60) transition is suggested to be accompani
ed by the increase of the fullerene solvation affecting thus the acidity of
methylene hydrogens in Ph2CH2 as well as the feasibility of their dissocia
tion. Also, photolysis of C-60 solutions in weakly acidic phenylacetylene i
s shown to lead to the addition of a varying number of phenylethinyl groups
to the fullerene core. (C) 2000 Elsevier Science B.V. All rights reserved.