Preparation of isolable ion-radical salt derived from TTF-based spin-polarized donor

Authors
Nakazaki, J Ishikawa, Y Izuoka, A Sugawara, T Kawada, Y
Citation
J. Nakazaki et al., Preparation of isolable ion-radical salt derived from TTF-based spin-polarized donor, CHEM P LETT, 319(3-4), 2000, pp. 385-390
Citations number
15
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
CHEMICAL PHYSICS LETTERS
ISSN journal
00092614 → ACNP
Volume
319
Issue
3-4
Year of publication
2000
Pages
385 - 390
Database
ISI
SICI code
0009-2614(20000317)319:3-4<385:POIISD>2.0.ZU;2-F
Abstract
Galvanostatic electrocrystallization of a TTF-based donor-radical (ETBN) ha s afforded an ion-radical salt. The radical site of ETBN is intact in the p repared salt and showed paramagnetic behavior. The salt is a semiconductor with conductivity of 10(-2) S/cm at room temperature. Conductivity and magn etic properties are explained as a new type of an ion-radical salt derived from a pi-conjugated donor-radical. (C) 2000 Elsevier Science B.V. All righ ts reserved.