Kinetic modeling of cool flames in CH3CHO-O-2 mixtures

Authors
Basevich, VY Vedeneev, VI Arutyunyan, VS
Citation
Vy. Basevich et al., Kinetic modeling of cool flames in CH3CHO-O-2 mixtures, CHEM PHYS R, 18(6), 2000, pp. 1081-1099
Citations number
14
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
CHEMICAL PHYSICS REPORTS
ISSN journal
10741550 → ACNP
Volume
18
Issue
6
Year of publication
2000
Pages
1081 - 1099
Database
ISI
SICI code
1074-1550(2000)18:6<1081:KMOCFI>2.0.ZU;2-I
Abstract
A kinetic mechanism of oxidation and combustion of CH3CHO - O-2 mixtures is proposed. Calculations by this mechanism of oxidation and two-stage self-i gnition of acetaldehyde - oxygen mixtures fit the available experimental da ta quite satisfactorily. The kinetic mechanism is used to depict propagatio n of a steady cool flame in this mixture. The cool flame model suggested is shown to be valid for practical computations.