An unexpected synthesis of an alpha, beta, gamma, delta-unsaturated ketonedue to an abnormal opening of benzylidene acetal by bromide anion

Authors
Wei, CQ Zhao, G Ding, Y
Citation
Cq. Wei et al., An unexpected synthesis of an alpha, beta, gamma, delta-unsaturated ketonedue to an abnormal opening of benzylidene acetal by bromide anion, CHIN J CHEM, 18(2), 2000, pp. 212-219
Citations number
8
Categorie Soggetti
Chemistry
Journal title
CHINESE JOURNAL OF CHEMISTRY
ISSN journal
1001604X → ACNP
Volume
18
Issue
2
Year of publication
2000
Pages
212 - 219
Database
ISI
SICI code
1001-604X(200003/04)18:2<212:AUSOAA>2.0.ZU;2-7
Abstract
An unexpected synthesis of an alpha, beta, gamma, delta-unsaturated ketone, which embodies a new type of oxy-carbon cyclic structure, was achieved, wh ile we tried to construct the taxane CB-ring system. Also, a series of abno rmal reaction phenomena was found to be related to the formation and reacti on of seven membered cyclic benzylidene acetal.