PHOTOCATALYTIC DEGRADATION OF LINDANE IN AQUEOUS-SOLUTION

Citation
A. Hiskia et al., PHOTOCATALYTIC DEGRADATION OF LINDANE IN AQUEOUS-SOLUTION, Pesticide science, 50(2), 1997, pp. 171-174
Citations number
13
Categorie Soggetti
Agriculture
Journal title
ISSN journal
0031613X
Volume
50
Issue
2
Year of publication
1997
Pages
171 - 174
Database
ISI
SICI code
0031-613X(1997)50:2<171:PDOLIA>2.0.ZU;2-Y
Abstract
Photolysis of lindane in aqueous solution, using near-visible and UV l ight (lambda > 320 nm) and in the presence of the polyoxometallate PW1 2O403-, results in its conversion to CO2 and HCl. Initial photodecompo sition takes place within a few minutes both in the presence and absen ce of dioxygen. The effective mineralization in the absence of dioxyge n suggests that OH radicals act as the primary oxidant in this case.