J. Etrillard et al., Low-frequency dynamics in molecular incommensurate composite: Specific heat of nonadecane/urea inclusion compound, EUROPH LETT, 49(5), 2000, pp. 610-616
We report the first very low-temperature specific-heat data of the incommen
surate n-nonadecane/urea inclusion compound. In addition to the contributio
n due to normal acoustic phonons, the results show a linear temperature? de
pendence of the specific heat below 1.5 K, assigned to the dynamical disord
er of the guest molecules. The excess heat capacity around 4.5 K reveals th
e low-frequency contribution of nondispersive modes. In contrast to the cas
e of modulated incommensurate compounds, no pinned sliding?; mode, phasan-l
ike mode, could be detected.