The composition in the surface region of the Heusler alloy NiMnSb has been
studied using angle-resolved X-ray photoemission spectroscopy low-energy el
ectron diffraction and spin-polarized inverse photoemission. The results ar
e? consistent with a generally Mu-Sb terminal layer, though the surface com
position is very sensitive to preparation. The surface composition has a cr
itical influence on the polarization near the Fermi level in spin-polarized
inverse photoemission. Under some conditions, the polarization at; the Fer
mi level far normal incidence inverse photoemission can reach values very c
lose to 100% above background.