Optimal estimation of atmospheric temperature and composition from limb sou
nding observations is extended to the direct retrieval of line-of-sight atm
ospheric structure that can be obtained in certain limb viewing geometries.
The approach is to divide the dataset into slightly overlapping chunks of
several atmospheric profiles and retrieve estimates for all profiles concur
rently. The method is made efficient due to the sparse nature of the matric
es involved. In the case where the number of radiance measurements is signi
ficantly larger than the length of the state vector, the computational effo
rt scales linearly with the number of profiles in the chunk. Prototype simu
lations, done for the EOS MLS experiment, show that application of this met
hod can give significant improvements in accuracy.