E. Stoyanova et D. Stoychev, ELECTROCHEMICAL ASPECTS OF THE IMMERSION TREATMENT OF ALUMINUM, Journal of Applied Electrochemistry, 27(6), 1997, pp. 685-690
The processes occurring during zinc immersion plating of aluminium hav
e been studied in alkaline medium. The mechanism of immersion zinc dep
osition on aluminium has been elucidated by studying the kinetics of t
he partial electrode reactions involved in this complex process. The d
iffusion of zincate ions has been shown to play a decisive role on the
cathodic reaction kinetics as well as on the global (cathodic and ano
dic) reaction rate.