ELECTRODEPOSITION OF COPPER AND NICKEL ON INBI ALLOY ELECTRODES

Citation
M. Azzag et al., ELECTRODEPOSITION OF COPPER AND NICKEL ON INBI ALLOY ELECTRODES, Journal of Applied Electrochemistry, 27(6), 1997, pp. 699-705
Citations number
20
Categorie Soggetti
Electrochemistry
ISSN journal
0021891X
Volume
27
Issue
6
Year of publication
1997
Pages
699 - 705
Database
ISI
SICI code
0021-891X(1997)27:6<699:EOCANO>2.0.ZU;2-J
Abstract
Electrodeposition of copper and nickel was investigated on the 67-33 w /w InBi soft alloy, which has a low melting point (72 degrees C), The electrochemical behaviour of this alloy was found to be similar to tha t of pure indium in a Watt's type bath. Direct and pulsed current tech niques were compared. For copper, a current density ranging from 500 t o 1000 A m(-2) was found to be suitable to obtain regular and shiny de posits at 25 degrees C, For nickel, at 45 degrees, the current density range used was 500 to 1250 A m(-2) to obtain good deposits, that were not affected by hydrogen evolution. Pulsed and direct currents were f ound to be equally efficient. The main interest of electrodeposition o n InBi alloy was the ease of removal of the alloy by simple melting, a nd consequently to make electrodes of unusual shapes which are normall y difficult to produce industrially, Only a small amount of InBi alloy remained in the inner part of the deposit.