Synthesis and structural characterization of [(mu-H)Ru-3(CO)(8){mu-S(CH2)(3)SH}(mu-dppe)] and [Ru-3(CO)(5){mu(2)-S(CH2)(3)S}(2)(eta(2)-dppe)] (dppe =Ph2PCH2CH2PPh2)

Authors
Kabir, SE Malik, KMA Rosenberg, E Siddiquee, TA
Citation
Se. Kabir et al., Synthesis and structural characterization of [(mu-H)Ru-3(CO)(8){mu-S(CH2)(3)SH}(mu-dppe)] and [Ru-3(CO)(5){mu(2)-S(CH2)(3)S}(2)(eta(2)-dppe)] (dppe =Ph2PCH2CH2PPh2), INORG CH C, 3(3), 2000, pp. 140-142
Citations number
23
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
INORGANIC CHEMISTRY COMMUNICATIONS
ISSN journal
13877003 → ACNP
Volume
3
Issue
3
Year of publication
2000
Pages
140 - 142
Database
ISI
SICI code
1387-7003(200003)3:3<140:SASCO[>2.0.ZU;2-P
Abstract
The reaction of 1,3-propanedithiol with [Ru-3(CO)(10)(mu-dppe)] (2) at 66 d egrees C afforded the thiolate complexes [(mu-H)Ru-3(CO)(8){mu-S(CH2)(3)SH} (mu-dppe)] (6) and [Ru-3(CO)(5){mu(2)-S(CH2)(3)S}(2)(eta(2)-dppe)] (7) in 2 5 and 23% yields respectively. Compound 6 is formed by simple oxidative add ition of one of the S-H bonds of 1,3-propanedithiol while the structurally unique 7 consists of an open triruthenium cluster with four terminal and on e asymmetrically bridged carbonyl groups, two doubly bridged propanedithiol ate ligands and a chelating dppe ligand. (C) 2000 Elsevier Science S.A. All rights reserved.